Bis(tri-2-pyridyl­amine)­nickel(II) bis­(perchlorate)

نویسندگان

  • Shi Wang
  • Wenrui He
  • Wei Huang
چکیده

In the title compound, [Ni(C(15)H(12)N(4))(2)](ClO(4))(2), the Ni(II) atom lies on an inversion center and is octa-hedrally coordinated by the N atoms of two tridentate tri-2-pyridyl-amine ligands. The two perchlorate anions are disordered over two sites with a refined occupancy ratio of 0.528 (19):0.472 (19).

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Bis{2-meth­oxy-6-[3-(methyl­amino)propyl­imino­meth­yl]phenolato}nickel(II) bis­(perchlorate)

The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N...

متن کامل

Bis{2-formyl-4-methyl-6-[(tri-2-pyridyl­meth­yl)imino­meth­yl]phenolato}nickel(II)

The title compound, [Ni(C(25)H(19)N(4)O(2))(2)], which was obtained by the reaction of nickel(II) perchlorate with 2,6-diformyl-4-methyl-phenol and (tri-2-pyridylmeth-yl)amine in methanol solution, is a discrete monometallic complex. The Ni(II) atom is six-coordinated by the phenolate O, imine N and pyridine N atoms from two tridentate Schiff base ligands in a distorted NiN(4)O(2) octa-hedral g...

متن کامل

Bis(di-2-pyridyl­amine-κ2 N,N′)bis­(thio­cyanato-κN)nickel(II)

The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa-hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl-amine (Hdpa) ligands and two thio-cyanate anions. Both amine H atoms are involved in N-H⋯S hydrogen bonding, resulting in the formation of layers of inter-linked mol-ecules parallel to the ab plane, which are further held together by...

متن کامل

trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ2 N 2,N 3]bis­(methanol-κO)iron(II) bis­(perchlorate)

The title compound, [Fe(C12H8N4S)2(CH3OH)2](ClO4)2, crystallized in the solvent-free form from a methanol solution. The Fe(II) ion is located on a centre of inversion. The distorted N4O2 octa-hedral coordination geometry is formed by two N,N'-chelating equatorial 2,5-bis-(pyridin-2-yl)-1,3,4-thia-diazole ligands and axially coordinating methanol coligands, resulting in the mononuclear trans-(N ...

متن کامل

Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)

Each Cu atom in the dinuclear centrosymmetric title complex, [Cu(2)Br(2)(C(14)H(17)N(3))(2)](ClO(4))(2), is ligated in a distorted square-pyramidal geometry (τ = 0.31) by a tridentate bis-[2-(2-pyrid-yl)eth-yl]amine ligand, and by two bridging Br atoms. In addition, the dinuclear species is stabilized by two hydrogen-bonded perchlorate anions.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2010